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This study aimed to better understand nitrate transport in the soil system in a part of the state of North Rhine-Westphalia, in Germany, and to aid in the development of groundwater protection plans. An advection-diffusion (AD) cell was used in a miscible displacement experiment setup to characterize nitrate transport in 12 different soil samples from the study area. The three nitrate sorption isotherms were tested to define the exact nitrate interaction with the soil matrix. Soils varied in their properties which in its turn explain the variations in nitrate transport rates. Soil texture and organic matter content showed to have the most important effect on nitrate recovery and retardation. The miscible displacement experiment indicated a decrease in retardation by increasing sand fraction, and an increase in retardation by increasing soil organic matter content. Soil samples with high sand fractions (up to 94 %) exhibited low nitrate sorption capacity of less than 10 %, while soils with high organic matter content showed higher sorption of about 30 %. Based on parameterization for nitrate transport equation, the pore water velocity for both sandy and loamy soils were significantly different (P < 0.001). Pore water velocity in sandy soil (about 4 x 10 high 3 m/s) was about 100 to 1000 larger than in loamy soils (8.7 x 10 high 5 m/s). On the other hand, the reduction in nitrate transport in soils associated with high organic matter was due to fine pore pathways clogged by fine organic colloids. It is expected that the existing micro-phobicity increased the nitrate recovery from 9 to 32 % resulting in maximum diffusion rates of about 3.5 x 10 high 5 m/s2 in sandy soils (sample number CS-04) and about 1.4 x 10 high 7 m/s2 in silt loam soils (sample number FS-02).
Although many German monitoring sites report declines of NOx concentrations, NO2-concentrations actually stagnate or even increase quite often. Various analyses have identified the altered compositions of nitrogen oxides (NO2/NOx-ratio) emitted by motor vehicles (resulting in an increase of primary NO2-emissions) as well as the chemical environmental conditions (mainly ground level ozone) as the main causes. The chemical conversion of NO to NO2 is often parameterized in dispersion calculations of exhaust emissions. A widely applied conversion model is the so-called Romberg approach from 1996. However, the Romberg approach has to be re-evaluated to accommodate the above-mentioned conditions. This article presents an adjustment to the Romberg approach in accordance with the measured data from 2000 to 2006, taking into consideration substantially higher NO2/NOx-ratios especially for higher NOx-concentrations. Model calculations with OSPM (Operational Street Pollution Model) including its internal chemistry module are able to reproduce very well the trends in the measured annual NO2-concentrations over a 10 year period. The relevant parameters for variations between the years are the NOx-emissions, primary NO2-emissions, ozone concentrations, wind conditions, and background concentrations. A simplified chemistry model based on annual mean NOx- and NO2-concentrations, and background ozone concentrations, as well as primary NO2-emissions is presented as a better method than the updated Romberg approach. This model simulates the annual mean NO2-concentrations much more accurately than the conventional and the updated Romberg approaches.
Road markings are an essential component of a safe road. In particular, the optical guidance at night and under wet conditions rates high. Special surface textures of road markings can enhance the nighttime visibility during wetness, but they can lead on the other hand to noise emission during passages of vehicles and thus annoy residents. In the present study the tyre/road marking noise is analysed based on two different measurement methods for traffic noise: Several different road markings with increased nighttime visibility during wetness were overrun and the noise was determined by controlled coast-by measurements as well as close-proximity measurements. For both measuring methods the averaged A-weighted sound pressure levels were determined and an analysis of the third octave spectra was performed in order to identify annoying tonal components. The results of both measurement methods were compared with each other. Limitations of the individual measurement methods were overcome by combining the data. Properties of road marking noise depending on the texture of the marking are discussed in relation to those of road surface noise. The results will help specifying road marking texture types that ensure less annoyance and at the same time good visibility at wetness and night-time.
In Europe, in situ measurements of sound reflection and airborne sound insulation of noise barriers are usually done according to CEN/TS 1793-5. This method has been improved substantially during the EU funded QUIESST collaborative project. Within the same framework, an inter-laboratory test has been carried out to assess the repeatability and reproducibility of the newly developed method when applied to real-life samples, including the effect of outdoor weather variability and sample ageing. This article presents the statistical analysis of the inter-laboratory test results, and the values of the repeatability and the reproducibility, both in one-third octave bands and for the single-number ratings. The estimated reproducibility values can be used as the extended measure of uncertainty at the 95% credibility level in compliance with the ISO GUM. The repeatability and reproducibility values associated with airborne sound insulation are also compared with the corresponding values for laboratory measurements in building acoustics and an acceptable agreement is found.
Structured road markings are becoming popular as edge line on high speed roads, ensuring night time visibility (retroreflection) during rain. These markings are often also "audio-tactile": vehicles (un)intentionally driving over it may produce much more tyre/road sound, which may be observed in the vehicle but also in the vicinity. The sound increase inside the car can be considered as a positive side effect, as it alarms the driver and may be very helpful for the prevention of "doze off" traffic accidents. The sound increase perceived outside the car however, may have a positive aspect as it can warn people on the emergency lane about the approaching vehicle, but it may as well annoy people living around. A method for the assessment of the acoustic properties of audio-tactile markings has been developed. It is mainly based on the "Close Proximity" (CPX) method, an ISO method intended for the acoustic assessment of pavements. The results of measurement campaigns with CPX trailers in Belgium and Germany according to a specially designed procedure are presented. The feasibility of the method is discussed. The research has been carried out in the frame of the standardization activities of the CEN working group CEN/TC226/WG2 "Horizontal signalization".
This article reports on a two-year study (2006 to 2008) of the distribution of de-icing salts (NaCl) applied to the road and the influence of traffic on the effective times of the de-icing salts. The research was focused on the needed resting periods of de-icing salts on road surfaces. The study used sensors installed in two lanes of the Motorway A4 in the area of the Dresden-Hellerau Highway Surveillance Center (Germany), to measure air and ground temperatures, wind speed and direction, liquid film thicknesses and residual quantities of salt on the road surface during ongoing traffic at 5-minute intervals. The authors conclude with four observations that can be useful for applying de-icing salts more judiciously: preventive spreading is only sensible if applied timely, i.e. immediately prior to icing events to be expected; the time-frame for preventive spreading on the dry road surface is maximum 60 minutes and on the moist road surface maximum 120 minutes; by increasing spreading densities in preventive spreading, this timeframe cannot be extended; it is completely sufficient if the spreading width is adjusted in such a way that the outer wheel tracks are also covered by the spreading. Distribution across the entire width of the lane will be caused by the rolling traffic within a few minutes.
Measuring and characterizing airborne particulate matter (PM) is an important research area because PM can lead to impacts on health and to visibility reduction, material damage and groundwater pollution. In regard to road dust, suspension and re-suspension and the contribution of non-exhaust PM to total traffic emissions are expected to increase as a result of predicted climate scenarios. European environmental regulations have been enforced to reduce exhaust particle emissions from road traffic, but little attention has been paid to reducing non-exhaust coarse particle emissions due to traffic. Therefore, a monitoring program for coarse PM has been initiated in early 2013 to assess the predicted increase in the abundance of non-exhaust particles. Particle sampling was performed with the passive-sampler technique Sigma-2. The subsequent single-particle analysis allows for characterization of individual particles, determination of PM size distribution, and calculation of PM mass concentrations. Two motorways n ear Cologne (Koeln), Germany were selected as sampling sites, and the experimental setup in the field was realized with a so-called twin-site method. The present study reports single-particle analysis data for samples collected between May 31, 2013 and May 30, 2014. Coarse PM, generated through multi-source mechanisms, consists of, e.g., tire-wear, soot aggregates, and mineral dust. The highest mass concentration occurs at both motorways in spring, and the observed PM mainly contains traffic-abrasion particles. The field measurements show that the minimum PM concentration was found in the 5 to 12-°C temperature range, whereas the maximum concentration was observed in both the "5 to 5-°C and the 12 to 24-°C ranges, in agreement with previous laboratory measurements. Correlation between super-coarse (d p 10"80 μm, geometric equivalent diameter) PM concentration and precipitation displays a significant increase in concentration with decreasing number of precipitation events (dry weather periods).