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This study aimed to better understand nitrate transport in the soil system in a part of the state of North Rhine-Westphalia, in Germany, and to aid in the development of groundwater protection plans. An advection-diffusion (AD) cell was used in a miscible displacement experiment setup to characterize nitrate transport in 12 different soil samples from the study area. The three nitrate sorption isotherms were tested to define the exact nitrate interaction with the soil matrix. Soils varied in their properties which in its turn explain the variations in nitrate transport rates. Soil texture and organic matter content showed to have the most important effect on nitrate recovery and retardation. The miscible displacement experiment indicated a decrease in retardation by increasing sand fraction, and an increase in retardation by increasing soil organic matter content. Soil samples with high sand fractions (up to 94 %) exhibited low nitrate sorption capacity of less than 10 %, while soils with high organic matter content showed higher sorption of about 30 %. Based on parameterization for nitrate transport equation, the pore water velocity for both sandy and loamy soils were significantly different (P < 0.001). Pore water velocity in sandy soil (about 4 x 10 high 3 m/s) was about 100 to 1000 larger than in loamy soils (8.7 x 10 high 5 m/s). On the other hand, the reduction in nitrate transport in soils associated with high organic matter was due to fine pore pathways clogged by fine organic colloids. It is expected that the existing micro-phobicity increased the nitrate recovery from 9 to 32 % resulting in maximum diffusion rates of about 3.5 x 10 high 5 m/s2 in sandy soils (sample number CS-04) and about 1.4 x 10 high 7 m/s2 in silt loam soils (sample number FS-02).
In most of the existing highway capacity manuals, level of service (LOS) of freeway weaving segments and ramp junctions is traditionally defined by the speed, volume or density in critical areas of merge, diverge and weaving manoeuvres. In that traditional concept several capacity values of different critical areas (merge, diverge, weaving) as well as upstream and downstream basic freeway segments within the influence areas are evaluated separately. In this paper, a new model which considers the total segment of freeway merge, diverge, and weaving as an entire object is introduced. A combined volume-to-capacity ratio is used for defining the LOS of the total segment. According to the probability and queuing theory, the volume-to-capacity ratio of the whole segment can be considered as a combination of volume-to-capacity ratios in the different critical areas under consideration. The parameters of the new model can be calibrated with field data. Those parameters are functions of the number of lanes on the freeways, the number of lanes in the on-ramps or off-ramps, the length of the acceleration, deceleration, or weaving sections. Varying the model parameters the function can be fitted to the existing capacity models for different types of weaving segments or ramp junctions. With this model, the traffic quality (LOS) can be obtained directly as a function of the volumes on the freeway and on the on-ramp or off-ramp respectively. The new model has the following advantages: a) a uniform function for all types of freeway weaving segments and ramp junctions, b) traffic quality assessment for all critical areas under investigation in one step, and c) easy calibration. The new model will be incorporated into the new edition of the German Highway Capacity Manual (HBS 201X).