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This study aimed to better understand nitrate transport in the soil system in a part of the state of North Rhine-Westphalia, in Germany, and to aid in the development of groundwater protection plans. An advection-diffusion (AD) cell was used in a miscible displacement experiment setup to characterize nitrate transport in 12 different soil samples from the study area. The three nitrate sorption isotherms were tested to define the exact nitrate interaction with the soil matrix. Soils varied in their properties which in its turn explain the variations in nitrate transport rates. Soil texture and organic matter content showed to have the most important effect on nitrate recovery and retardation. The miscible displacement experiment indicated a decrease in retardation by increasing sand fraction, and an increase in retardation by increasing soil organic matter content. Soil samples with high sand fractions (up to 94 %) exhibited low nitrate sorption capacity of less than 10 %, while soils with high organic matter content showed higher sorption of about 30 %. Based on parameterization for nitrate transport equation, the pore water velocity for both sandy and loamy soils were significantly different (P < 0.001). Pore water velocity in sandy soil (about 4 x 10 high 3 m/s) was about 100 to 1000 larger than in loamy soils (8.7 x 10 high 5 m/s). On the other hand, the reduction in nitrate transport in soils associated with high organic matter was due to fine pore pathways clogged by fine organic colloids. It is expected that the existing micro-phobicity increased the nitrate recovery from 9 to 32 % resulting in maximum diffusion rates of about 3.5 x 10 high 5 m/s2 in sandy soils (sample number CS-04) and about 1.4 x 10 high 7 m/s2 in silt loam soils (sample number FS-02).
Measuring and characterizing airborne particulate matter (PM) is an important research area because PM can lead to impacts on health and to visibility reduction, material damage and groundwater pollution. In regard to road dust, suspension and re-suspension and the contribution of non-exhaust PM to total traffic emissions are expected to increase as a result of predicted climate scenarios. European environmental regulations have been enforced to reduce exhaust particle emissions from road traffic, but little attention has been paid to reducing non-exhaust coarse particle emissions due to traffic. Therefore, a monitoring program for coarse PM has been initiated in early 2013 to assess the predicted increase in the abundance of non-exhaust particles. Particle sampling was performed with the passive-sampler technique Sigma-2. The subsequent single-particle analysis allows for characterization of individual particles, determination of PM size distribution, and calculation of PM mass concentrations. Two motorways n ear Cologne (Koeln), Germany were selected as sampling sites, and the experimental setup in the field was realized with a so-called twin-site method. The present study reports single-particle analysis data for samples collected between May 31, 2013 and May 30, 2014. Coarse PM, generated through multi-source mechanisms, consists of, e.g., tire-wear, soot aggregates, and mineral dust. The highest mass concentration occurs at both motorways in spring, and the observed PM mainly contains traffic-abrasion particles. The field measurements show that the minimum PM concentration was found in the 5 to 12-°C temperature range, whereas the maximum concentration was observed in both the "5 to 5-°C and the 12 to 24-°C ranges, in agreement with previous laboratory measurements. Correlation between super-coarse (d p 10"80 μm, geometric equivalent diameter) PM concentration and precipitation displays a significant increase in concentration with decreasing number of precipitation events (dry weather periods).